Tech Speak: Advanced Oxidation
Head: Advanced Oxidation
Deck: Ozone and ultraviolet sanitation both
have their pros and cons - but new technologies combine both for superior results
Byline: Ronald L. Barnes
Pristine, sanitized, non-toxic water is the goal of all
recreational water owners and operators. However, not all chemical sanitation
and oxidation treatments are created equal.
The challenges of eliminating
toxic chemicals and their byproducts while maintaining water sanitation and
oxidation have led consumers and health officials to search for
chemical-limited (or reduced chemical) solutions to water treatment.
Unfortunately, this search has opened the door to highly promoted "alternative
sanitizers," some of which are less effective than others.
This has inspired some
manufacturers to develop Advanced Oxidation Processing (AOP) solutions. AOP
devices produce hydroxyl radicals (OH-), which constitute a highly
potent oxidizer. Hydroxyl radicals are created when ozone is used in
conjunction with intense ultraviolet (UV) light and water. To produce hydroxyl
radicals, ozone is injected into water that is irradiated by VUV light, or
water vapor within a VUV ozone generator.
Ozone and UV
Ozone systems oxidize
contaminants such as E. coli, Legionella, and most bacteria and
viruses very rapidly. Yet some of the most toxic contaminants can be difficult
to destroy, even with ozone. A high ozone concentration is necessary for the
more resistant strains of Cryptosporidium, for example - this parasite
calls for an ozone generator package geared toward large commercial pools and
water features.
Meanwhile, ultraviolet
sterilizers have been widely used in the water industry for decades. The
method destroys dangerous organisms' DNA, preventing their reproduction.
Though UVC is often touted as having the capacity to convert chloramines to
free chlorine, only high pressure UVB lamps have been shown to possess that
capability.
However, by combining the two
technologies of ozone generation and low pressure UVC (a wavelength found in
germicidal lamps), the Advanced Oxidation Process has emerged as a new
solution for oxidizing and sanitizing hard-to-remove contaminants, such as
Cryptosporidium's cystic form, compound chloramines and pharmaceutical
residuals.

What is AOP?
AOP is the conversion of ozone
by ultraviolet rays on the UVC wavelength, in the presence of water, to form
high-energy hydroxyl radicals.
Hydroxyls function in a manner
similar to hydrogen peroxide, which is increasingly common for use as an
oxidation shock in pools. However, the hydroxyl radical energy level
generated in the AOP process is higher than that generated by hydrogen
peroxide alone.
